Even with a 5 link rear you can't have toe, camber, castor and all that stuff (at the rear)...because you still have a fixed 90deg / 90deg hub on the end of a parallel Diff.
So if summats 'off' it should be the front end, the tracking etc should - even with an independent 4 wheel aligner be set up as if the rear is the parallel base line bouncing the laser lines forward
Aim for front Toe in half a deg (1/16 to 1/8inch) Camber 0.75 to 1.0 deg negative, Castor 4 to 5 deg, (note castor not a diy job to adjust)
Deffo check Richard's comment above as that had slipped on mine last year dropping into a big pot hole whilst on lock turning at a junction