I know you said she did some longer runs; however, hopefully she'll find the Polestar 2 will give her enough range to get her to client site and back home without needing to charge.
Yep - that was the thinking behind getting an advertised 400+mile range
What I will add is that one of my colleague's wives was pushed down a similar path by her company - she also has to do site visits all over the UK. She was pushed the EV cc route about two years ago and hasn't had one incident when having to charge away from home.
In my own experience, for the most part people seem to sit in their cars, more often than not using the 30-mins quick charge to have a nap or catch up on calls/emails. I've never seen people milling around charge points (more chance of that in the services themselves, most of which seem to have fallen into a state of disrepair, especially when compared to many of our European neighbours motorway side conveniences) and the closest I've come to any interaction is the rare person who wants to chat with you about EV range, etc, whilst waiting for their own car to charge (more common in good weather!).
It's good to hear, but unfortunately not much consolation to the other half. It's never happened to me, and I know hundreds of women who've never been attacked walking home, but that doesn't make Bex feel any safer walking home on her own. I appreciate it's difficult for us blokes to put ourselves in the female mindset.